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Marseilles soap

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The oils

Oil As the source prints it Share
Olive Oil (virgin / refined / olive oil) Olive-oil · 100 lb 100.0 %

How it is made

Process Full-boiled
Alkali caustic soda ley of 36° Baumé · 54 lb · 36° Bé
Superfat Not stated
Water as the source states it
Iodine value 85
INS 106

This is a boiled soap. A kettle soap has its excess alkali salted out and drawn off before framing, so the recipe states the alkali charged, never the alkali the bar keeps. Read as a modern cold-process recipe it would be lye-heavy.

What the numbers say

Hardness 17 below 29–54
Cleansing 0 below 12–22
Conditioning 81 above 44–69
Bubbly lather 0 below 14–46
Creamy lather 17 16–48

Computed from the fatty acids of the fats above. The bands are what the craft has settled on, not chemistry — a bar outside one is not wrong.

The source

Watt gives the alkali twice: 54 lb of ley at 36° Baumé, "and this amount of ley represents about 15·50 of solid caustic soda — the utmost amount that must be applied to each 100 lbs. of the oil used". Olive oil at a typical 190 mg KOH/g needs about 13.6 lb of NaOH for complete saponification, so the kettle is charged roughly 14 % over. That is not a negative superfat: the excess leaves with the spent lye when the soap is salted out. This is the clearest case in the corpus of why a boiled formula cannot be read as a cold-process recipe.

Alexander Watt, The Art of Soap-Making: A Practical Handbook of the Manufacture of Hard and Soft Soaps, Toilet Soaps, Etc., Crosby Lockwood and Co., London, 1884, p.37. The Art of Soap-Making: A Practical Handbook of the Manufacture of Hard and Soft Soaps, Toilet Soaps, Etc. · read 2026-09-22

Read from the Internet Archive OCR of the Cornell University Library copy. Page numbers are taken from OCR'd running headers and may be one out where the header digits were damaged.

Read from a scan rather than a proofread transcription, so the figures are checked against the book’s own printed total where it prints one.

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