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Liquid soaps

Coconut liquid hand soap

A glass pump bottle of clear pale gold liquid hand soap beside a jar of translucent soap paste and a dish of white coconut oil on a deep green backdrop

A clear, quick-lathering liquid soap for the sink: half coconut oil, with olive oil to soften it and castor oil to hold the lather once diluted. It is made as a potassium hydroxide paste and diluted to 25 % soap for a pump bottle, or further for a foaming dispenser.

Skill
Advanced
Method
Hot process
Batch
500 g of oils about 975 g of batter
Hands-on
1 h 30 min
Cure
2 weeks
Gel phase
In the pot it gels as it cooks
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What you need

For 500 g of oils, which fills two or three 1-litre pump bottles once diluted. Weigh everything, liquids included.

Coconut Oil · 50.0 % 250 g 8.82 oz
Olive Oil · 35.0 % 175 g 6.17 oz
Castor Oil · 15.0 % 75 g 2.65 oz
Potassium hydroxide (KOH) · the lye, 90 % pure; if your label says otherwise, weigh 125.8 g at 85 % or 112.5 g at 95 % 118.8 g 4.19 oz
Distilled water · for a 25 % lye solution 356.4 g 12.57 oz
Boiling water, for the clarity test · to dissolve 28 g of cooked paste and see whether it runs clear 59 ml
Distilled water, for diluting the paste · boiling; 2428 g less the weight of the cooked paste, about 1453 g if the cook lost no steam and more if it did 1453 g 51.25 oz
Superfat
3.5 %
Temperatures
Lye solution cooled below 82 °C (180 °F), oils at 65 to 71 °C (150 to 160 °F), cooked on low

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Method

  1. Get ready

    Put on sealed goggles, nitrile gloves and long sleeves, and keep them on until the paste is cooked. Weigh 250 g of coconut oil, 175 g of olive oil and 75 g of castor oil into a slow cooker of 4.5 litres or more, 356.4 g of distilled water into a heat-proof jug and 118.8 g of potassium hydroxide flakes into a dry container, then close the flake tub at once.
  2. Make the lye solution

    At an open window, add the flakes to the water a little at a time, stirring, never the water to the flakes. It fizzes loudly and runs hotter than sodium hydroxide; let it cool below 82 °C (180 °F), and keep it away from aluminium, tin and zinc, which it attacks, giving off hydrogen.
  3. Warm the oils

    Melt the coconut oil in the slow cooker on low, stir in the olive and castor oils and bring them to 65 to 71 °C (150 to 160 °F).
  4. Blend to a stiff paste

    Pour the lye solution into the oils and stick blend in bursts of a minute or two, stirring between them. Keep going through the false traces, when the batter thickens and then separates or thins again, until it sets into a stiff, opaque paste that stretches like taffy and the blender can barely move.
  5. Cover and cook

    Put the lid on and leave the cooker on low. Check after 15 to 20 minutes and again 15 to 20 minutes later, stirring back any separated liquid and stirring the paste down if it swells, then stir every 30 to 45 minutes.
  6. Cook until translucent

    Over 2 to 3 hours the paste turns pale gold and translucent from the edges inwards. It is ready to test when no opaque, creamy patches come up as you fold it over.
  7. Test a spoonful in boiling water

    Stir 28 g (1 oz) of paste into 59 ml (2 fl oz) of boiling water until it dissolves, and let it cool. Clear or faintly hazy means the paste is done; milky, or with an oily film on top, means another hour of cooking and a second test.
  8. Weigh the paste

    Turn off the cooker, let the paste cool and weigh all of it. It will weigh less than the 975.2 g that went in, because steam left the pot, and the dilution needs the real figure.
  9. Work out the water

    The paste holds 606.9 g of soap: the 500 g of oils plus the 106.9 g of pure potassium hydroxide in 118.8 g of 90 % flakes. At 25 % soap, a good strength for a pump bottle, that makes 2428 g of liquid soap however much steam the cook drove off, so the water to add is 2428 g minus your paste's weight, about 1.49 g for every gram of paste if it lost none; the liquid soap dilution calculator does the same sum.
  10. Dilute it overnight

    Break the paste into a large pot or jar and pour on all but the last 150 g of that water, boiling hot. Stir gently without whipping up foam, cover it and leave it overnight; the next day, at room temperature, add the rest only if it is still thicker than you want.
  11. Judge the thickness with water, not salt

    This soap is mostly coconut and castor oil, with too little oleic acid for salt to thicken it, so it pours thinner than a shop soap. If you want it thicker, dilute your next jar of paste with less water; diluted soap cannot be thickened back.
  12. Dilute further for a foaming pump

    For a foaming dispenser, mix one part of the finished soap with one and a half parts of distilled water, which brings it to about 10 % soap.
  13. Settle and bottle

    Leave the soap covered for a week or two so any haze sinks, then pour the clear soap off the sediment into washed and dried bottles.
  14. Keep it clean

    Diluted, this is three-quarters water or more, and it can grow bacteria and mould once they get in: never top up a half-empty bottle, and keep the rest as paste in a closed jar, diluting a little at a time. To keep diluted soap for long, or to sell it, it needs a preservative that works at pH 9 to 10, and soap for sale needs a challenge test as well.

Tips

  • The lye assumes potassium hydroxide flakes of 90 % purity, the usual label figure. If your label says otherwise, enter it in the calculator before you weigh: flakes purer than the figure you used make the paste lye-heavy.
  • Coconut-rich potassium soap swells as it saponifies, so use a pot four to five times the volume of the batch and never leave it unattended in the first hour.
  • To scent it, stir half a teaspoon of essential oil into 85 g of warm soap first and wait half an hour: some oils, citrus ones especially, thin or cloud liquid soap. If the sample stays clear, use 0.5 to 1 % of the diluted soap's weight.
  • Use distilled water for the paste and the dilution. Minerals in tap water form insoluble soaps that show as haze and sediment.

Why make it

A pump-bottle hand soap for people who would rather make their own. Half coconut oil gives a quick, clear lather in cool water, and olive and castor oil soften it, cleansing 34 and conditioning 48 on our scale: milder than a dish soap, but a cleanser rather than a moisturiser. Washing with plain soap and water is what public health bodies recommend for clean hands, and the US FDA found no evidence that washes sold with added germ-killing ingredients do better than plain soap and water. Unscented, it suits people who avoid fragrance. The caveats: it has no preservative, so once diluted keep it in small batches and never top a bottle up, and in hard water it leaves more scum than a shop-bought detergent.

Sources

What tradition, makers' experience and research say about soaps like this, each labelled for what it is. It is not medical advice, and no soap treats a skin condition: if you have one, ask a doctor or pharmacist.

What the numbers say

  • Lauric acid 24.6 %
  • Myristic acid 9.5 %
  • Palmitic acid 9.5 %
  • Stearic acid 2.8 %
  • Ricinoleic acid 13.3 %
  • Oleic acid 28.5 %
  • Linoleic acid 5.9 %
  • Other 8.2 %

Saturated : unsaturated 52 : 48

Hardness 46 29–54
Cleansing 34 above 12–22
Conditioning 48 44–69
Bubbly lather 47 above 14–46
Creamy lather 26 16–48

Computed from the fatty acids of the fats above. The bands are what the craft has settled on, not chemistry — a bar outside one is not wrong.

From the guides

All guides

Where these proportions come from

Our own formulation, set between the two liquid soap blends in David Fisher's Complete Photo Guide to Soap Making, his bubbly coconut-rich one and his mild olive-rich one: half coconut oil for a quick, clear lather, 35 % olive oil to soften it and 15 % castor oil to carry the lather through dilution. The superfat is 3.5 %, half a point above the usual 0 to 3 % for liquid soap, because the published saponification ranges of coconut and olive oil are wide enough that at 3 % the worst case just tips into spare lye.

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